詹姆斯·柯登
James Kimberley Corden
饰：Self - Host
Dave Berry
Dave Berry
饰：Voice Over
Holly Samos
Holly Samos
饰：Voice Over
阿黛尔
Adele
饰：Herself
杰玛·阿特登
Gemma Arterton
饰：Herself
Jonny Buckland
Jonny Buckland
饰：Himself
威尔·查平
Will Champion
饰：Himself
汤姆·戴利
Tom Daley
饰：Himself - Presenter
帕洛玛·菲丝
Paloma Faith
饰：Herself
Rebecca Ferguson
Rebecca Ferguson
饰：Herself
乔治男孩
Boy George
饰：Himself
大卫·格鲁
David Grohl
饰：Himself - Presenter
Ben Howard
Ben Howard
饰：Himself - Performer
婕西·J
Jessie J
饰：Herself
摇摆不定男生
Jack the Lad Swing
饰：Themselves
凯瑟琳·詹金斯
Katherine Jenkins
饰：Herself
Little Mix
Little Mix
饰：Themselves
贝纳尼丝·玛尔洛
Berenice Marlohe
饰：Herself - Presenter
蒙福之子乐队
Mumford & Sons
饰：Themselves - Performers
缪斯
Muse
饰：Themselves - Performers
德莫特·欧莱瑞
Dermot O'Leary
饰：Himself - Presenter
克里斯托弗·弗朗西斯·奥申
Christopher Francis Ocean
饰：Himself
单向乐队
One Direction
饰：Themselves - Performers
瑞塔·奥拉
Rita Ora
饰：Herself
莎伦·奥斯本
Sharon Osbourne
饰：Herself - Presenter
西蒙·佩吉
Simon Pegg
饰：Himself - Presenter
阿什丽·罗伯茨
Ashley Roberts
饰：Herself
乔纳森·罗斯
Jonathan Ross
饰：Himself - Presenter
阿黛尔·艾梅丽·桑德
Emeli Sandé
饰：Herself - Performer
艾德·希兰
Ed Sheeran
饰：Himself
Louis Smith
Louis Smith
饰：Himself - Presenter
拉菲·斯波
Rafe Spall
饰：Himself
泰勒·斯威夫特
Taylor Swift
饰：Herself - Performer
贾斯汀·汀布莱克
Justin Randall Timberlake
饰：Himself - Performer
Jessie Ware
Jessie Ware
饰：Herself
杰克·怀特霍尔
Jack Whitehall
饰：Himself - Presenter
罗伯特·彼得·西米利安·威廉姆斯
Robert Peter Maximillian Williams
饰：Himself - Performer
拉娜·德雷
Lana Del Rey
饰：Herself
Bat for Lashes
饰：Self
Sara Cox
Sara Cox
饰：Self
卓丹·邓
Jourdan Dunn
饰：Self - Presenter
布莱恩·费瑞
Bryan Ferry
饰：Self - Presenter
尼克·格里姆肖
Nick Grimshaw
饰：Self - Presenter
加尔文·哈里斯
Calvin Harris
饰：Self
JLS
饰：Themselves
帕迪·麦吉尼斯
Paddy McGuinness
饰：Self
尼欧(NE-YO)
Ne-Yo
饰：Self
科琳妮·柏利·雷
Corinne Bailey Rae
饰：Self
丹妮丝·凡·奥滕
Denise Van Outen
饰：Self
Jo Whiley
Jo Whiley
饰：Self
Emma Willis
Emma Willis
饰：Self
陈智林
Jaime Winston
饰：Self
达蒙·奥尔本
Damon Albarn
饰：Self - Presenter
伊基·阿塞莉娅
Iggy Azalea
饰：Self
约翰·巴克兰德
Jon Buckland
饰：Self (as Coldplay)
艾里珊·钟
Alexa Chung
饰：Self
Jamie Cullum
Jamie Cullum
饰：Self
卢克·伊万斯
Luke Evans
饰：Self
Caroline Flack
饰：Self
Preeya Kalidas
Preeya Kalidas
饰：Self
Annie MacManus
饰：Self
Stephen Mulhern
饰：Self
奥利·莫尔斯
Olly Murs
饰：Self
梅兰妮·尼玛
Melanie Nyema
饰：Self - Singer
迪韦恩·托马斯
Dywayne Thomas
饰：Self
Mitch Winehouse
Mitch Winehouse
饰：Self
Mark Wright
饰：Self