立木文彦
Fumihiko Tachiki
饰：Gendô Ikari (voice: Japanese version)
山口由里子
Yuriko Yamaguchi
饰：Ritsuko Akagi (voice: Japanese version)
清川 元梦
Motomu Kiyokawa
饰：Kôzô Fuyutsuki (voice: Japanese version)
宫村优子
Yûko Miyamura
饰：Asuka Langley Sôryû (voice: Japanese version)
石田彰
Ishida Akira
饰：Kaworu Nagisa (voice: Japanese version)
戴夫·维滕博格
Dave Wittenberg
饰：Seele (voice: English version)
麦人
Mugihito
饰：Keel Lorentz (voice: Japanese version)
塔利辛·贾夫
Taliesin Jaffe
饰：JSSDF Soldier (voice: English version)
蒂凡尼·格兰特
Tiffany Grant
饰：Asuka Langley Sohryuu (voice: English version)
Laura Chapman
Laura Chapman
饰：Dr. Akagi (voice: English version)
Tristan MacAvery
Tristan MacAvery
饰：Gendo Ikari (voice: English version)
Kurt Stoll
Kurt Stoll
饰：Kensuke (voice: English version)
子安武人
Takehito Koyasu
饰：Shigeru Aoba (voice: Japanese version)
结城比吕
Yuuki Hiro
饰：Makoto Hyûga (voice: Japanese version)
长泽 美树
Miki Nagasawa
饰：Maya Ibuki (voice: Japanese version)
Sue Ulu
Sue Ulu
饰：Ritsuko Akagi (voice: English version)
布雷特·韦弗
Brett Weaver
饰：Toji (voice: English version)
Amanda Winn
Amanda Winn
饰：Rei Ayanami,Yui Ikari (voice: English version) (as Amanda Winn)
斯派克·斯宾塞
Spike Spencer
饰：Shinji Ikari (voice: English version)
Jason Lee
Jason Lee
饰：Shigeru Aoba (voice: English version)
Tom Booker
Tom Booker
饰：Keel Lorenz (voice: English version)
Allison Keith
Allison Keith
饰：Misato Katsuragi (voice: English version)
Aaron Krohn
Aaron Krohn
饰：Ryoji Kaji,Kaoru Nagisa (voice: English version)
Amy Seeley
Amy Seeley
饰：Maya Ibuki (voice: English version)
Kimberly Yates
Kimberly Yates
饰：Hikari (voice: English version)
Keith Burgess
Keith Burgess
饰：Makoto Hyuga (voice: English version)
Riley Barber
Riley Barber
饰：JSSDF Commander (voice: English version)
Thomas Greene
Thomas Greene
饰：Additional Voices (voice: English version)
Ryan Paregien
Ryan Paregien
饰：Additional Voices (voice: English version)
Traci Shannon
Traci Shannon
饰：Additional Voices (voice: English version)
林原惠美
林原 めぐみ
饰：绫波丽
三石琴乃
Kotono Mitsuishi
饰：葛城美里
绪方惠美
Ogata Megumi绪方惠美
饰：碇真嗣
优希比吕
Hiro Yuuki
饰：Makoto Hyûga
阿曼达·韦恩·李
Amanda Winn Lee
饰：Rei Ayanami
山寺宏一
山寺 宏一
川村万梨阿
かわむら まりあ
川村万梨阿
かわむら まりあ
饰：配音
矢岛晶子
Akiko Yajima
松本 保典
Yasunori Matsumoto
长嶝高士
Takashi Nagasako
泽木 郁也
Ikuya Sawaki
山野井仁
Jin Yamanoi
永野广一
Kôichi Nagano
菅原淳一
Sugawara Junichi
涉谷茂
Shibuya Shigeru
Ryan Bartley
Ryan Bartley
饰：Rei Ayanami (2019 re-dub),
Clifford Chapin
饰：Kaworu Nagisa (2019 re-dub),
Greg Chun
Greg Chun
饰：Ryoji Kaji (2019 re-dub),
亨利·迪特曼
Henry Dittman
饰：Council Member C,
D.C.道格拉斯
D.C. Douglas
饰：Keel Lorenz (2019 re-dub),
Billy Kametz
Billy Kametz
饰：Shigeru Aoba (2019 re-dub),
Stephanie McKeon
饰：Asuka Langely Soryu (2019 re-dub),
Christine Marie Cabanos
饰：Maya Ibuki (2019 re-dub),
雷·蔡斯
Ray Chase
饰：Gendo Ikari (2019 re-dub),
Daniel Mk Cohen
饰：Makoto Hyuga (2019 re-dub),
Lucien Dodge
Lucien Dodge
饰：Seele,Soldier (2019 re-dub),/
JP Karliak
JP Karliak
饰：Kouzou Fuyutsuki (2019 re-dub),
艾瑞卡·林贝克
Erica Lindbeck
饰：Ritsuko Akagi (2019 re-dub),
Casey Mongillo
饰：Shinji Ikari (2019 re-dub),